Author: Sheila R. Buxton
Publisher: Prentice Hall
ISBN:
Category : Chemistry, Organic
Languages : en
Pages : 268

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Book Description
Takes the reader step-by-step from the structures of simple molecules, such as methane, to the basic shapes of biologically important macromolecules, such as proteins and nucleic acids. Deals with the concept of chirality, which is often overlooked by many texts. Chirality is approached by firstly explaining the stereochemistry of compounds with one stereogenic centre, then dealing with compounds having two or more stereogenic centres before focusing on compounds possessing axes of chirality. The importance of stereochemistry in a wide variety of transformations (for example addition reactions, eliminations, and cycloadditions), is discussed. The final chapters describe the application of stereocontrol in asymmetric synthesis, indicating the use of chiral auxiliaries and chiral catalysts in modern chemistry.

Author: Arnold Eiloart
Publisher:
ISBN:
Category : Stereochemistry
Languages : en
Pages : 134

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Book Description

Author: Arnold Eiloart
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 102

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Book Description

Author: David A. Lightner
Publisher: John Wiley & Sons
ISBN: 9780471354055
Category : Science
Languages : en
Pages : 496

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Book Description
A unique guide to variable temperature CD spectroscopy and its application in organic chemistry This timely, original, thought-provoking work looks at organic stereochemistry from the perspective of circular dichroism (CD), using variable temperature CD spectroscopy to determine the conformation or absolute configuration of chiral molecules. With an emphasis on the analysis of optically active ketones and the carbonyl chromophore, the authors demonstrate the advantages of this highly sensitive spectroscopic tool for obtaining stereochemical information in diverse areas of organic chemistry, biochemistry, and medicinal/pharmaceutical chemistry. They combine detailed examples of stereochemical analysis with clear, thorough presentations, correlating chiroptical data with molecular mechanics calculations as well as data from NMR spectroscopy and other spectroscopic techniques. In addition, they provide a systematic survey of the professional literature, featuring an extraordinary collection of original CD spectra run at varying temperatures. Coverage includes: * Chiroptical measurements: CD and ORD (Optical Rotatory Dispersion) * Conformational analysis of compounds ranging from simple cyclic ketones to polycyclics * Conjugated and homoconjugated systems * Stereochemistry of the carbon-carbon double bond * Stereochemistry from exciton coupling of two or more chromophores * An interesting historical account of the development of stereochemical concepts

Author: F. D. Gunstone
Publisher: Longman Publishing Group
ISBN:
Category : Stereochemistry
Languages : en
Pages : 112

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Book Description

Author: Ernest L. Eliel
Publisher: John Wiley & Sons
ISBN: 0470147520
Category : Science
Languages : en
Pages : 533

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Book Description
This seminal series, first edited by Ernest Eliel, responsible for some of the major advances in stereochemistry and the winner of the ACS Priestley Medal in 1996, provides coverage of the major developments of the field of stereochemistry. The scope of this series is broadly defined to encompass all fields of chemical and biological sciences that are founded on molecular and supramolecular interactions. Insofar as chemical, physical, and biological properties are determined by molecular shape and structure, the importance of stereochemistry is fundamental to and consequential for all natural sciences. Topics in Stereochemistry serves as a multidisciplinary series that enriches all of chemistry. Aimed at advanced students, university professors and teachers as well as researchers in pharmaceutical, agricultural, biotechnological, polymer, materials, and fine chemical industries, Topics in Stereochemistry publishes definitive and scholarly reviews in stereochemistry and has long been recognized as the gold standard reference work in this field. Covering the effect of chirality on all aspects of molecular interaction from the fundamental physical chemical properties of molecules and their molecular physics to the application of chirality in new areas such as its applications in materials science, Topics in Stereochemistry explores a wide variety of properties, both physical and chemical of isomers with a view to their applications in a number of disciplines from biochemistry to materials science.

Author: Bishal Baishya
Publisher: Createspace Independent Publishing Platform
ISBN: 9781523712229
Category :
Languages : en
Pages : 80

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Book Description
This Book on Stereo-chemistry is really a must for all students of High school, College & University Level (UG). Some parts of the contents has been written by understanding different sources which are reliable & authentic.Table of Contents01. Description of Term02. History of the Term 03. Drawing of organic molecules04. Some important concepts in stereo chemistry05. Some Definitions06. Optical activity07. Optical purity08. Projection Formulas 09. Visualizing a Fischer projection 09. Absolute configuration-R, S-Convention 10. CIP Rules11. Assigning absolute configurations in Cyclic molecules12. Assigning absolute configurations in Fischer molecules13. Geometric isomerism (also known as cis-trans isomerism or E-Z isomerism)14. The E-Z systemThis book also contains Some Selected Problems for Practice by Students.

Author: Sheila R. Buxton
Publisher:
ISBN: 9787506233996
Category : Stereochemistry
Languages : en
Pages : 252

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Book Description

Author: Anil V. Karnik
Publisher: Elsevier
ISBN: 012821063X
Category : Science
Languages : en
Pages : 620

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Book Description
Stereochemistry: The Three-Dimensional Chemistry draws on the knowledge of its expert authors, providing a systematic treatment on the fundamental aspects of stereochemistry, covering conformational aspects, configurational aspects, effects of bulkiness, stereoelectronic effects on properties of molecules, and the genesis of enantiomerism, among other topics. Visuals and exercises are included to consolidate the principles learned, and the contents are carefully structured to prepare readers for predicting and organizing reaction components to obtain desired stereochemical outcomes. This book is an indispensable guide for all those exploring stereochemistry within their work. The principles of stereochemistry are fundamental to understanding chemical behavior and can provide insights into a whole range of problems, from unusual selectivity and unexpected behaviors, to abnormally fast reactions and surprising biochemical preferences. However, understanding and exploring these 3D effects can be difficult within a 2D medium. This book has been designed to address this problem, providing foundational guidance on the principles and applications of stereochemistry that are fully supported by multimedia visuals. Combines foundational concepts and definitions with examples of stereochemistry in practice Highlights the conformational and configurational impact of atomic arrangement on chemical behavior Outlines methods of analysis Provides practical exercises and detailed multimedia visuals to support learning

Author: Ira Remsen
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages :

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Book Description