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Book Description
Takes the reader step-by-step from the structures of simple molecules, such as methane, to the basic shapes of biologically important macromolecules, such as proteins and nucleic acids. Deals with the concept of chirality, which is often overlooked by many texts. Chirality is approached by firstly explaining the stereochemistry of compounds with one stereogenic centre, then dealing with compounds having two or more stereogenic centres before focusing on compounds possessing axes of chirality. The importance of stereochemistry in a wide variety of transformations (for example addition reactions, eliminations, and cycloadditions), is discussed. The final chapters describe the application of stereocontrol in asymmetric synthesis, indicating the use of chiral auxiliaries and chiral catalysts in modern chemistry.
Book Description
This Book on Stereo-chemistry is really a must for all students of High school, College & University Level (UG). Some parts of the contents has been written by understanding different sources which are reliable & authentic.Table of Contents01. Description of Term02. History of the Term 03. Drawing of organic molecules04. Some important concepts in stereo chemistry05. Some Definitions06. Optical activity07. Optical purity08. Projection Formulas 09. Visualizing a Fischer projection 09. Absolute configuration-R, S-Convention 10. CIP Rules11. Assigning absolute configurations in Cyclic molecules12. Assigning absolute configurations in Fischer molecules13. Geometric isomerism (also known as cis-trans isomerism or E-Z isomerism)14. The E-Z systemThis book also contains Some Selected Problems for Practice by Students.
Book Description
Stereochemistry: The Three-Dimensional Chemistry draws on the knowledge of its expert authors, providing a systematic treatment on the fundamental aspects of stereochemistry, covering conformational aspects, configurational aspects, effects of bulkiness, stereoelectronic effects on properties of molecules, and the genesis of enantiomerism, among other topics. Visuals and exercises are included to consolidate the principles learned, and the contents are carefully structured to prepare readers for predicting and organizing reaction components to obtain desired stereochemical outcomes. This book is an indispensable guide for all those exploring stereochemistry within their work. The principles of stereochemistry are fundamental to understanding chemical behavior and can provide insights into a whole range of problems, from unusual selectivity and unexpected behaviors, to abnormally fast reactions and surprising biochemical preferences. However, understanding and exploring these 3D effects can be difficult within a 2D medium. This book has been designed to address this problem, providing foundational guidance on the principles and applications of stereochemistry that are fully supported by multimedia visuals. Combines foundational concepts and definitions with examples of stereochemistry in practice Highlights the conformational and configurational impact of atomic arrangement on chemical behavior Outlines methods of analysis Provides practical exercises and detailed multimedia visuals to support learning
Book Description
This seminal series, first edited by Ernest Eliel, responsible for some of the major advances in stereochemistry and the winner of the ACS Priestley Medal in 1996, provides coverage of the major developments of the field of stereochemistry. The scope of this series is broadly defined to encompass all fields of chemical and biological sciences that are founded on molecular and supramolecular interactions. Insofar as chemical, physical, and biological properties are determined by molecular shape and structure, the importance of stereochemistry is fundamental to and consequential for all natural sciences. Topics in Stereochemistry serves as a multidisciplinary series that enriches all of chemistry. Aimed at advanced students, university professors and teachers as well as researchers in pharmaceutical, agricultural, biotechnological, polymer, materials, and fine chemical industries, Topics in Stereochemistry publishes definitive and scholarly reviews in stereochemistry and has long been recognized as the gold standard reference work in this field. Covering the effect of chirality on all aspects of molecular interaction from the fundamental physical chemical properties of molecules and their molecular physics to the application of chirality in new areas such as its applications in materials science, Topics in Stereochemistry explores a wide variety of properties, both physical and chemical of isomers with a view to their applications in a number of disciplines from biochemistry to materials science.
Book Description
Organic Chemistry Guide is a concise, yet comprehensive book, which helps you to understand the course and grasp the big picture. The principles are introduced in an easy-to-follow manner, while nearly 200 figures help you on the way to success. More than 600 problems with solutions makes learning efficient, and develops practical skills to tinker with organic molecules and reactions. The book is addressed to students of chemistry, biology and medicine, as well as to the self-taught science enthusiasts. Join the fellowship of the rings and chains with Organic Chemistry Guide. Part I - structure of molecules, bond-line drawings and isomers. Part II - organic nomenclature, functional groups and classes of compounds, systematic names and IUPAC rules, naming molecules, and drawing molecules from names. Part III - stereochemistry, geometry of molecules, conformations, Newman projections, cyclohexane chair and ring flipping. Part IV - stereoisomers, rules of priority, E/Z and cis/trans isomers, asymmetric carbon atom and R/S configurations, wedge and dash bonds, chirality and optical activity, enantiomers and diastereoisomers. Part V - formal charges, partial charges, delocalization and resonance, drawing resonance structures, inductive effect, electron donating and withdrawing groups. Part VI - acidic and basic nature of organic molecules, position of equilibrium and acid-base reactions.
Book Description
K.C. Nicolaou - Winner of the Nemitsas Prize 2014 in Chemistry This book is a must for every synthetic chemist. With didactic skill and clarity, K. C. Nicolaou and E. Sorensen present the most remarkable and ingenious total syntheses from outstanding synthetic organic chemists. To make the complex strategies more accessible, especially to the novice, each total synthesis is analyzed retrosynthetically. The authors then carefully explain each synthetic step and give hints on alternative methods and potential pitfalls. Numerous references to useful reviews and the original literature make this book an indispensable source of further information. Special emphasis is placed on the skillful use of graphics and schemes: Retrosynthetic analyses, reaction sequences, and stereochemically crucial steps are presented in boxed sections within the text. For easy reference, key intermediates are also shown in the margins. Graduate students and researchers alike will find this book a gold mine of useful information essential for their daily work. Every synthetic organic chemist will want to have a copy on his or her desk.